Papers › Unraveling the Catalytic Effect of Hydrogen Adsorption on Pt Nanoparticle Shape-Change
Unraveling the Catalytic Effect of Hydrogen Adsorption on Pt Nanoparticle Shape-Change
Cameron J. Owen, Nicholas Marcella, Yu Xie, Jonathan Vandermause, Anatoly I. Frenkel, Ralph G. Nuzzo, Boris Kozinsky
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The activity of metal catalysts depends sensitively on dynamic structural changes that occur during operating conditions. The mechanistic understanding underlying such transformations in small Pt nanoparticles (NPs) of ∼1-5 nm in diameter, commonly used in hydrogenation reactions, is currently far from complete. In this study, we investigate the structural evolution of Pt NPs in the presence of hydrogen using reactive molecular dynamics (MD) simulations and X-ray spectroscopy measurements. To gain atomistic insights into adsorbate-induced structural transformation phenomena, we employ a combination of MD based on first-principles machine-learned force fields with extended X-ray absorption fine structure (EXAFS) measurements. Simulations and experiments provide complementary information, mutual validation, and interpretation. We obtain atomic-level mechanistic insights into `order-disorder' structural transformations exhibited by highly dispersed heterogeneous Pt catalysts upon exposure to hydrogen. We report the emergence of previously unknown candidate structures in the small Pt NP limit, where exposure to hydrogen leads to the appearance of a `quasi-icosahedral' intermediate symmetry, followed by the formation of `rosettes' on the NP surface. Hydrogen adsorption is found to catalyze these shape transitions by lowering their temperatures and increasing the apparent rates, revealing the dual catalytic and dynamic nature of interaction between nanoparticle and adsorbate. Our study also offers a new pathway for deciphering the reversible evolution of catalyst structure resulting from the chemisorption of reactive species, enabling the determination of active sites and improved interpretation of experimental results with atomic resolution.
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