Papers › Mapping the Space of Chemical Reactions Using Attention-Based Neural Networks

Mapping the Space of Chemical Reactions Using Attention-Based Neural Networks

9 Dec 2020arXiv:2012.06051archive 2025-07-28

Philippe Schwaller, Daniel Probst, Alain C. Vaucher, Vishnu H. Nair, David Kreutter, Teodoro Laino, Jean-Louis Reymond

Organic reactions are usually assigned to classes containing reactions with similar reagents and mechanisms. Reaction classes facilitate the communication of complex concepts and efficient navigation through chemical reaction space. However, the classification process is a tedious task. It requires the identification of the corresponding reaction class template via annotation of the number of molecules in the reactions, the reaction center, and the distinction between reactants and reagents. This work shows that transformer-based models can infer reaction classes from non-annotated, simple text-based representations of chemical reactions. Our best model reaches a classification accuracy of 98.2%. We also show that the learned representations can be used as reaction fingerprints that capture fine-grained differences between reaction classes better than traditional reaction fingerprints. The insights into chemical reaction space enabled by our learned fingerprints are illustrated by an interactive reaction atlas providing visual clustering and similarity searching.

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ClusteringGeneral Classification

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AdamAttentionAttention DropoutBERTDense ConnectionsDropoutLayer NormalizationLinear LayerLinear Warmup With Linear DecayMulti-Head AttentionResidual ConnectionSoftmaxWeight DecayWordPiece

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