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Empowering Machines to Think Like Chemists: Unveiling Molecular Structure-Polarity Relationships with Hierarchical Symbolic Regression

25 Jan 2024arXiv:2401.13904archive 2025-07-28

Siyu Lou, Chengchun Liu, Yuntian Chen, Fanyang Mo

Thin-layer chromatography (TLC) is a crucial technique in molecular polarity analysis. Despite its importance, the interpretability of predictive models for TLC, especially those driven by artificial intelligence, remains a challenge. Current approaches, utilizing either high-dimensional molecular fingerprints or domain-knowledge-driven feature engineering, often face a dilemma between expressiveness and interpretability. To bridge this gap, we introduce Unsupervised Hierarchical Symbolic Regression (UHiSR), combining hierarchical neural networks and symbolic regression. UHiSR automatically distills chemical-intuitive polarity indices, and discovers interpretable equations that link molecular structure to chromatographic behavior.

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Feature EngineeringSymbolic Regressionregression

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TLC

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