Papers › Computing the local pressure in molecular dynamics simulations

Computing the local pressure in molecular dynamics simulations

11 Nov 2011arXiv:1111.2705links table onlyarchive 2025-07-28

Thomas Lion, Rosalind J. Allen

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Computer simulations of inhomogeneous soft matter systems often require accurate methods for computing the local pressure. We present a simple derivation, based on the virial relation, of two equivalent expressions for the local (atomistic) pressure in a molecular dynamics simulation. One of these expressions, previously derived by other authors via a different route, involves summation over interactions between particles within the region of interest; the other involves summation over interactions across the boundary of the region of interest. We illustrate our derivation using simulations of a simple osmotic system; both expressions produce accurate results even when the region of interest over which the pressure is measured is very small.

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